Study on preparation and adsorbability of new sensitive material to toxic organophosphorous vapors

ZHANG Qian~1; LI Shan-mao~2; GAO Min~1; BI Guo-xiang~3

doi:10.13873/j.1000-97872006.02.008

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Study on preparation and adsorbability of new sensitive material to toxic organophosphorous vapors

更新时间：2025-09-11

- Study on preparation and adsorbability of new sensitive material to toxic organophosphorous vapors
- Issue 2, Pages: 24-26(2006)
- 作者机构：
  
  1. 军械工程学院弹药工程系
  2. 防化指挥工程学院化学防护系
  3. 河北裕丰实业股份有限公司
- 作者简介：
- 基金信息：
- DOI：10.13873/j.1000-97872006.02.008
  CLC： TB34
- Published：2006
- 稿件说明：
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[1]张倩,李善茂,高敏,秘国祥.新型含磷毒剂敏感材料制备及吸附性能研究[J].传感器与微系统,2006(02):24-26.

ZHANG Qian~1, LI Shan-mao~2, GAO Min~1, et al. Study on preparation and adsorbability of new sensitive material to toxic organophosphorous vapors[J]. 2006, (2): 24-26.
[1]张倩,李善茂,高敏,秘国祥.新型含磷毒剂敏感材料制备及吸附性能研究[J].传感器与微系统,2006(02):24-26. DOI： 10.13873/j.1000-97872006.02.008.

ZHANG Qian~1, LI Shan-mao~2, GAO Min~1, et al. Study on preparation and adsorbability of new sensitive material to toxic organophosphorous vapors[J]. 2006, (2): 24-26. DOI： 10.13873/j.1000-97872006.02.008.

摘要

化学传感器的灵敏度和选择性主要通过敏感材料的选择来确定。研究和开发适当的材料使气体传感器的敏感特性达到最优是研究气体传感器的重要步骤。利用1

3双-（2-羟基六氟-2-丙基）-丙烯和表氯醇缩聚制备了一种新型的含磷毒剂敏感膜材料——环氧树脂-B;利用石英晶体微天平（QCM）法对氟多元醇（FPOL）和环氧树脂-B 2种膜材料进行了性能评价

结果表明:新型膜材料环氧树脂-B对含磷毒剂的选择性好、吸附性能力强

是一种可用于野外含磷毒剂实时侦检的实用敏感膜材料。

Abstract

The sensitivity and selectivity of chemical sensors are controlled by sensitive materials mainly.Researching and developing novel sensitive materials are the important progress optimizing chemical sensors.A new sensitive material—epoxy resin-B is prepared by the polycondensation of 1

3-di（2-hydroxydexafluoro-2-propyl） propene with epichlorohydrin.The properties of both materials of FPOL and the epoxy resin-B are evaluated by quartz crystal microbalances（QCM）.The result shows that the epoxy resin-B is a sensitive material with high selectivity and adsorbability to toxic organophosphorous vapors and it can be used in field at real-time.

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references

化学战剂的分析测试进展 [J]. 边归国. 分析测试技术与仪器 . 2004(02)

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