1. 中国科学院水库水环境重点实验室中国科学院重庆绿色智能技术研究院
2. 中国科学院地球内部物质高温高压重点实验室中国科学院地球化学研究所
纸质出版:2017
移动端阅览
[1]陈鸿珍,王光伟,徐愿坚,徐丽萍,李和平.Li_2CO_3/YSZ电极制备方法对CO_2传感器性能的影响[J].传感器与微系统,2017,36(05):6-10+18.
CHEN Hong-zhen, WANG Guang-wei, XU Yuan-jian, et al. Effects of Li2CO3/YSZ electrode preparing methods on characteristics of CO2 sensor[J]. 2017, 36(5): 6-10+18.
[1]陈鸿珍,王光伟,徐愿坚,徐丽萍,李和平.Li_2CO_3/YSZ电极制备方法对CO_2传感器性能的影响[J].传感器与微系统,2017,36(05):6-10+18. DOI: 10.13873/j.1000-9787(2017)05-0006-05.
CHEN Hong-zhen, WANG Guang-wei, XU Yuan-jian, et al. Effects of Li2CO3/YSZ electrode preparing methods on characteristics of CO2 sensor[J]. 2017, 36(5): 6-10+18. DOI: 10.13873/j.1000-9787(2017)05-0006-05.
借助X射线衍射和扫描电镜
研究烧结、熔融和承载三种典型Li
2
CO
3
/YSZ敏感电极制作方法对CO
2
传感器性能的影响。结果表明
三种方法均能制备出致密的Li
2
CO
3
/YSZ敏感电极薄膜
并在实验条件(500℃
CO
2
浓度范围(318
5
76 800)×10
-6
)下对待测气体中的CO
2
具有准确的响应;熔融法制作的电极薄膜颗粒较其他两种方法大
且由于电极体系中涉及Li
2
ZrO
3
和Li
2
CO
3
的相互转化反应
使得传感器长时间稳定性受到影响。
By means of XRD analysis and SEM observation
effects of Li
2
CO
3
/YSZ electrodes prepared by different methods( sintering
melting
and carrying) on properties of the potentiometric CO
2
sensors are studied. The results indicate that all of the three methods can prepare compact Li
2
CO
3
/YSZ electrode films
and sensors made up of them response correctly to the CO
2
alterations at 500 ℃ and CO
2
concentration range of 318
576 800 ×10
-6
. Melting prepared electrode film exhibits bigge
r size of particles compared with the other two methods. And due to the conversion reaction between Li
2
Zr O
3
and Li
2
CO
3
in this electrode system
the long term stability of sensors made up of it is affected.
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