1. 重庆科技大学化学化工学院
2. 遵义师范学院化学化工学院
纸质出版:2025
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先思维, 王光伟, 张鹏. 基于半导体异质结构的二氧化氮传感器研究进展[J]. 传感器与微系统, 2025,(6):1-5+11.
先思维, 王光伟, 张鹏. 基于半导体异质结构的二氧化氮传感器研究进展[J]. 传感器与微系统, 2025,(6):1-5+11. DOI: 10.13873/J.1000-9787(2025)06-0001-05.
半导体复合形成的p-n型、n-n型和p-p型异质结构可促进载流子(电子或空穴)跨越结界面迁移,使结界处受电子耗尽层或空穴积累层变化的影响而出现势垒区范围扩大或缩小。基于这些异质结构的二氧化氮(NO
2
)传感器不但响应值大幅提升,而且灵敏度、选择性、稳定性、检测限和运行温度显著改善,在NO
2
检测领域表现出明显优势。可基于金属氧化物、过渡金属硫属化合物和其他半导体构建异质结构NO
2
传感器,根据这些传感器的响应规律,可望通过材料和结构设计调控载流子迁移效率和效果,研制出性能更佳的NO
2
传感器,在NO
2
检测中发挥出更大的应用价值。
武天飞,杨先军.NO_2气体传感器的研究现状[J].传感器与微系统,2024(04).
赵天宇,王霞,吕玲玲,龙世佳.基于CuPc-SnO_2复合纳米多孔材料的NO_2传感器研究[J].传感器与微系统,2023(08).
王博,刘继江,王烜赫,高云鹏,尹春岳,马丽娜.用于NO_2传感器的NiO@C复合材料性能研究[J].传感器与微系统,2023(03).
郝维勋,刘成利,王硕,程义,李敏,杨永超.基于SnS_2/In_2O_3异质结的室温NO_2传感性能研究[J].传感器与微系统,2022(09).
Zhong Hong Shi,Yu Jen Hsiao,Sheng Po Chang,Shoou Jinn Chang.Synthesis and characterization of an oxygen-controlled CuO/SnO2 sensor for NO2 detection[J].Sensors and Actuators: B. Chemical,2024.
Senlin Li,Lingmin Yu,Chuantao Zhang,Xiang Li,Lei Cao,Hongbo Du,Xinhui Fan.Controllable synthesis of heterostructured CuO–ZnO microspheres for NO2 gas sensors[J].Sensors and Actuators: B. Chemical,2024.
R. Abimaheshwari,R. Abinaya,J. Archana,C. Muthamizhchelvan,M. Navaneethan,S. Harish.In-situ growth of vertically stacked 2D SnS2/SnS heterostructure for highly sensitive and rapid room temperature NO2 gas sensor[J].Journal of Alloys and Compounds,2024.
Haixia Xing,Xinlei Li,Shupeng Sun,Baoyu Huang,Xiaogan Li.Low-temperature NO2 sensor based on γ-In2Se3/In2O3 nanoflower heterojunction[J].Sensors and Actuators: B. Chemical,2024.
Yanqiao Ding,Bingsheng Du,Xuezheng Guo,Yingchun Dong,Maozhu Zhang,Weifeng Jin,Cao Gao,Di Peng,Yong He.An ultrasensitive NO2 gas sensor based on a NiO-SnO2 composite with a sub-ppb detection limit at room temperature[J].Sensors and Actuators: B. Chemical,2024.
Sufaid Shah,Shahid Hussain,Salah Ud Din,Abdulnasser M. Karami,You Tianyan,Mingsong Wang,Guiwu Liu,Guanjun Qiao.Improved ppb level SnO2@In2O3 sensor induced by In2O3 nanoparticles embedded on SnO2 nanoflower for superior NO2 sensing performance[J].Ceramics International,2024.
Zhiping Liang,Yu Zhang,Mingyuan Wang,Siwei Liu,Xiangzhao Zhang,Shuangying Lei,Junlin Liu,Guanjun Qiao,Guiwu Liu.Facile preparation of flower-like NiO/In2O3 composite for sensitively and selectively detecting NO2 at room and lower temperatures[J].Applied Surface Science,2024.
Sonika Kodan,Ashwani Kumar,Amit Sanger,Alisha Arora,V.K. Malik,Ramesh Chandra.Vertically aligned MoSe2-WS2 nanoworms heterojunction towards room temperature NO2 gas sensors[J].Sensors and Actuators: B. Chemical,2024.
Liang Zhiping,Wang Mingyuan,Liu Siwei,Hassan Mobashar,Zhang Xiangzhao,Lei Shuangying,Qiao Guanjun,Liu Guiwu.One-pot hydrothermal synthesis of self-assembled MoS2/WS2 nanoflowers for chemiresistive room-temperature NO2 sensors[J].Sensors and Actuators: B. Chemical,2024.
Yan Jinlong,Wang Yanyan,Yang Cheng,Deng Haoyuan,Hu Nantao.MoS2/MoO3 heterojunctions enabled by surface oxidization of MoS2 nanosheets for high-performance room-temperature NO2 gas sensing[J].Journal of Alloys and Compounds,2024.
Gao Rui,Zhang Tao,Zhang Xianfa,Gao Shan,Xu Yingming,Cheng Xiaoli,Gao Jinsheng,Zheng Ming,Zhou Xin,Huo Lihua.One-step controlled synthesis of ZnO-ZnSe hollow nanospheres with surface defects for selective detection of NO2[J].Applied Surface Science,2023.
Zhao Hu,Ge Wanyin,Tian Ye,Wang Pengtao,Li Xi,Liu Zhifu.Pr2Sn2O7/NiO heterojunction for ultra-fast and low operating temperature to NO2 gas sensing[J].Sensors and Actuators: A. Physical,2023.
Zhang Yiran,Wu Chunping,Xiao Bang,Yang Lin,Jiao Anqi,Li Ke,Chen Ting,Zhan Reggie,Huang Zhen,Lin He.Chemo-resistive NO2 sensor using La-doped WO3 nanoparticles synthesized by flame spray pyrolysis[J].Sensors and Actuators: B. Chemical,2022.
Sun Lixia,Hou Chaoyang,Sun Jianhua,Mo Qiulian,Han Jingyi,Bai Shouli,Luo Ruixian.One-step calcined equiatomic W and Zn precursors to synthesize heterojunction of ZnO/ZnWO4 for NO2 detection[J].Sensors and Actuators: B. Chemical,2022.
Liu Yanna,Li Sheng,Xiao Song,Du Ke.Down to ppb level NO2 detection by vertically MoS2 nanoflakes grown on In2O3 microtubes at room temperature[J].Colloids and Surfaces A: Physicochemical and Engineering Aspects,2022.
Hu Yaqing,Li Tingting,Zhang Jianhua,Guo Jingyu,Wang Weiwei,Zhang Dongzhi.High-sensitive NO2 sensor based on p-NiCo2O4/n-WO3 heterojunctions[J].Sensors and Actuators: B. Chemical,2022.
Zhang Xu,Liu Yaoda,Liu Hang,Liang Tingting,Zhang Pengfei,Dai Zhengfei.FeSe2/Hematite n-n heterojunction with oxygen spillover for highly efficient NO2 gas sensing[J].Sensors and Actuators: B. Chemical,2021.
Bai Xue,Lv He,Liu Zhuo,Chen Junkun,Wang Jue,Sun Baihe,Zhang Yang,Wang Ruihong,Shi Keying.Thin-layered MoS2 nanoflakes vertically grown on SnO2 nanotubes as highly effective room-temperature NO2 gas sensor[J].Journal of Hazardous Materials,2021.
Yang Shulin,Lei Gui,Xu Huoxi,Lan Zhigao,Wang Zhao,Gu Haoshuang.Metal Oxide Based Heterojunctions for Gas Sensors: A Review[J].Nanomaterials,2021.
Wang Wei,Zhang Yuanyi,Zhang Jinniu,Li Gang,Leng Deying,Gao Ying,Gao Jianzhi,Lu Hongbing,Li Xiaohui.Metal–organic framework-derived Cu2O–CuO octahedrons for sensitive and selective detection of ppb-level NO2 at room temperature[J].Sensors and Actuators: B. Chemical,2021.
Wei Liu,Ding Gu,Xiaogan Li.Detection of Ppb-level NO 2 using mesoporous ZnSe/SnO 2 core-shell microspheres based chemical sensors[J].Sensors and Actuators: B. Chemical,2020.
Qiangqiang Li,Ning Han,Kewei Zhang,Shouli Bai,Jian Guo,Ruixian Luo,Dianqing Li,Aifan Chen.Novel p-n heterojunction of BiVO 4 /Cu 2 O decorated with rGO for low concentration of NO 2 detection[J].Sensors and Actuators: B. Chemical,2020.
Shouli Bai,Kewei Zhang,YingYing Zhao,Qiangqiang Li,Ruixian Luo,Dianqing Li,Aifan Chen.rGO decorated NiO-BiVO 4 heterojunction for detection of NO 2 at low-temperature[J].Sensors and Actuators: B. Chemical,2020.
Wenwen Zeng,Yingzhi Liu,Jun Mei,Changyu Tang,Kun Luo,Shaomin Li,Haoran Zhan,Zhoukun He.Hierarchical SnO 2 –Sn 3 O 4 heterostructural gas sensor with high sensitivity and selectivity to NO 2[J].Sensors and Actuators: B. Chemical,2019.
Shouli Bai,Ke Tian,Hang Fu,Yongjun Feng,Ruixian Luo,Dianqing Li,Aifan Chen,Chung Chiun Liu.Novel α-Fe 2 O 3 /BiVO 4 heterojunctions for enhancing NO 2 sensing properties[J].Sensors & Actuators: B. Chemical,2018.
State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Environmentally Harmful Chemicals Analysis, Beijing University of Chemical Technology, Beijing 100029, China,Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China,State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Environmentally Harmful Chemicals Analysis, Beijing University of Chemical Technology, Beijing 100029, China,State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Environmentally Harmful Chemicals Analysis, Beijing University of Chemical Technology, Beijing 100029, China,State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Environmentally Harmful Chemicals Analysis, Beijing University of Chemical Technology, Beijing 100029, China,State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Environmentally Harmful Chemicals Analysis, Beijing University of Chemical Technology, Beijing 100029, China,State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Environmentally Harmful Chemicals Analysis, Beijing University of Chemical Technology, Beijing 100029, China,State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Environmentally Harmful Chemicals Analysis, Beijing University of Chemical Technology, Beijing 100029, China.On the construction of hollow nanofibers of ZnO-SnO 2 heterojunctions to enhance the NO 2 sensing properties[J].Sensors and Actuators: B. Chemical,2018.
Chao Yan,Hongbing Lu,Jianzhi Gao,Ying Zhang,Quanmin Guo,Haoxuan Ding,Yitao Wang,Fenfen Wei,Gangqiang Zhu,Zhibo Yang,Chunlan Wang.Improved NO 2 sensing properties at low temperature using reduced graphene oxide nanosheet–In 2 O 3 heterojunction nanofibers[J].Journal of Alloys and Compounds,2018.
Hai Yu,Tianye Yang,Zhiyang Wang,Zhifang Li,Qi Zhao,Mingzhe Zhang.p -N heterostructural sensor with SnO-SnO 2 for fast NO 2 sensing response properties at room temperature[J].Sensors & Actuators: B. Chemical,2018.
Ding Gu,Xiaogan Li,Yangyang Zhao,Jing Wang.Enhanced NO 2 sensing of SnO 2 /SnS 2 heterojunction based sensor[J].Sensors & Actuators: B. Chemical,2017.
Quan Thi Minh Nguyet,Nguyen Van Duy,Nguyen Thi Phuong,Nguyen Ngoc Trung,Chu Manh Hung,Nguyen Duc Hoa,Nguyen Van Hieu.Superior enhancement of NO 2 gas response using n - p - n transition of carbon nanotubes/SnO 2 nanowires heterojunctions[J].Sensors & Actuators: B. Chemical,2017.
Wenjun Yan,Ming Hu,Jiran Liang,Dengfeng Wang,Yulong Wei,Weiyi Zhang,Yuxiang Qin.Preparation and room temperature NO2-sensing performances of n-porous silicon/n-WO3 nanowires heterojunction[J].Materials Research Bulletin,2016.
C.W. Zou,J. Wang,W. Xie.Synthesis and enhanced NO2 gas sensing properties of ZnO nanorods/TiO2 nanoparticles heterojunction composites[J].Journal of Colloid And Interface Science,2016.
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