1. 宁波大学信息科学与工程学院
2. 电子科技大学光电科学与工程学院
纸质出版:2024
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王梓, 王佐硕, 简家文, 等. 基于BaZr0.8Y0.2O3-δ电解质的电流型NOx传感器[J]. 传感器与微系统, 2024,(2):12-16.
王梓, 王佐硕, 简家文, 等. 基于BaZr0.8Y0.2O3-δ电解质的电流型NOx传感器[J]. 传感器与微系统, 2024,(2):12-16. DOI: 10.13873/J.1000-9787(2024)02-0012-05.
氮氧化物(NO
x
)传感器是选择性催化还原(SCR)系统的重要组件之一。为了降低传统NO
x
传感器的工作温度,使用2%质量分数的NiO作为烧结助剂制备了质子导体BaZr
0.8
Y
0.2
O
3-δ
(BZY)电解质,研究了NiO烧结助剂对BZY电解质的相结构、微观形貌的影响。制备了基于BZY电解质的电流型NO
x
传感器。实验结果表明:该传感器在400℃时,对体积分数范围在10×10
-6
~250×10
-6
的NO
2
显示出良好的线性响应。同时,也表现出较高的灵敏度、良好的选择性和重复性。
Rokas Sažinas,Martin F. Sunding,Annett Thøgersen,Isao Sakaguchi,Truls Norby,Tor Grande,Jonathan M. Polfus.Surface reactivity and cation non-stoichiometry in BaZr1âxYxO3âδ (x = 0â0.2) exposed to CO2 at elevated temperature[J].Journal of Materials Chemistry A,2019.
Gang Chen,Yadan Luo,Wenkang Sun,Hailiang Liu,Yushi Ding,Ying Li,Shujiang Geng,Kai Yu,Guoqiang Liu.Electrochemical performance of a new structured low temperature SOFC with BZY electrolyte[J].International Journal of Hydrogen Energy,2018.
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Emiliana Fabbri,Daniele Pergolesi,Silvia Licoccia,Enrico Traversa.Does the increase in Y-dopant concentration improve the proton conductivity of BaZr 1 − x Y x O 3 − δ fuel cell electrolytes?[J].Solid State Ionics,2010.
Jianhua Tong,Daniel Clark,Michael Hoban,Ryan O'Hayre.Cost-effective solid-state reactive sintering method for high conductivity proton conducting yttrium-doped barium zirconium ceramics[J].Solid State Ionics,2010.
Masahiro Nagao,Takeshi Yoshii,Takashi Hibino,Mitsuru Sano,Atsuko Tomita.Electrochemical Reduction ofNO xat Intermediate Temperatures Using a Proton[J].Electrochemical and Solid State Letters,2005.
Ralf Moos.A Brief Overview on Automotive Exhaust Gas Sensors Based on Electroceramics[J].International Journal of Applied Ceramic Technology,2005.
Wensheng Wang,Anil V. Virkar.Ionic and electron–hole conduction in BaZr 0.93 Y 0.07 O 3− δ by 4-probe dc measurements[J].Journal of Power Sources,2004.
Pio Forzatti.Present status and perspectives in de-NO x SCR catalysis[J].Applied Catalysis A, General,2001.
Serge Zhuiykov,Takashi Nakano,Akira Kunimoto,Noboru Yamazoe,Norio Miura.Potentiometric NO x sensor based on stabilized zirconia and NiCr 2 O 4 sensing electrode operating at high temperatures[J].Electrochemistry Communications,2001.
T. Schober,H.G. Bohn.Water vapor solubility and electrochemical characterization of the high temperature proton conductor BaZr 0.9 Y 0.1 O 2.95[J].Solid State Ionics,2000.
Tetsuro Kobayashi,Katsushi Abe,Yoshio Ukyo,Hiroyasu Iwahara.Reduction of nitrogen oxide by steam electrolysis cell using a protonic conductor SrZr 0.9 Yb 0.1 O 3− α and the catalyst Sr/Al 2 O 3[J].Solid State Ionics,2000.
Tetsuro Kobayashi,Shinya Morishita,Katsushi Abe,Hiroyasu Iwahara.Reduction of nitrogen oxide by a steam electrolysis cell using a proton conducting electrolyte[J].Solid State Ionics,1996(P1).
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