上海应用技术大学化学与环境工程学院
纸质出版:2022
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司晨曦, 高翔, 曹可, 等. 基于Cu-BTC的2,4-二氯苯酚电化学传感器研究[J]. 传感器与微系统, 2022,(7):13-16.
基于Cu-BTC的2,4-二氯苯酚电化学传感器研究[J]. 2022, (7): 13-16.
司晨曦, 高翔, 曹可, 等. 基于Cu-BTC的2,4-二氯苯酚电化学传感器研究[J]. 传感器与微系统, 2022,(7):13-16. DOI: 10.13873/J.1000-9787(2022)07-0013-04.
基于Cu-BTC的2,4-二氯苯酚电化学传感器研究[J]. 2022, (7): 13-16. DOI: 10.13873/J.1000-9787(2022)07-0013-04.
利用水热合成法制备了金属有机框架(MOFs)材料—铜—1
3
5—苯三甲酸(Cu-BTC)。研制了一种基于Cu-BTC复合纳米导电碳粉(VXC—72)修饰玻碳电极(GCE)的电化学传感器,用于2
4—二氯苯酚(2
4—DCP)的敏感检测。利用循环伏安(CV)法和差分脉冲伏安(DPV)法研究传感电极Cu-BTC@VXC—72/GCE的电化学性能,确定了Cu-BTC︰VXC—72为1︰1.5(质量比)
磷酸盐缓冲液(PBS)pH值为7
以及扫描速度50 mV/s的最佳电化学响应条件。DPV结果表明:在最佳响应条件下,5×10
-7
~8×10
-6
mol/L的2
4—DCP浓度范围内,氧化峰电流与2
4—DCP浓度呈现良好的线性关系,检测限可达7.895×10
-8
mol/L;同时,Cu-BTC@VXC—72/GCE传感电极在2
4—DCP的敏感检测中表现出强的抗干扰能力和好的稳定性,20天连续测定后的氧化峰电流衰减不足20%。
利用水热合成法制备了金属有机框架(MOFs)材料—铜—1
3
5—苯三甲酸(Cu-BTC)。研制了一种基于Cu-BTC复合纳米导电碳粉(VXC—72)修饰玻碳电极(GCE)的电化学传感器,用于2
4—二氯苯酚(2
4—DCP)的敏感检测。利用循环伏安(CV)法和差分脉冲伏安(DPV)法研究传感电极Cu-BTC@VXC—72/GCE的电化学性能,确定了Cu-BTC︰VXC—72为1︰1.5(质量比)
磷酸盐缓冲液(PBS)pH值为7
以及扫描速度50 mV/s的最佳电化学响应条件。DPV结果表明:在最佳响应条件下,5×10
-7
~8×10
-6
mol/L的2
4—DCP浓度范围内,氧化峰电流与2
4—DCP浓度呈现良好的线性关系,检测限可达7.895×10
-8
mol/L;同时,Cu-BTC@VXC—72/GCE传感电极在2
4—DCP的敏感检测中表现出强的抗干扰能力和好的稳定性,20天连续测定后的氧化峰电流衰减不足20%。
氧化锌-氧化铜纳米复合物可见光诱导光催化降解2,4-二氯酚性能(英文) [J]. E.D.Sherly,J.Judith Vijaya,L.John Kennedy. 催化学报 . 2015(08)
Photoelectrocatalytic evaluation of EG-CeO 2 photoanode on degradation of 2,4-dichlorophenol [J] . Potlako J. Mafa,Bhekie B. Mamba,Alex T. Kuvarega. Solar Energy Materials and Solar Cells . 2020 (C)
Molecularly imprinted PEDOT on carbon fiber paper electrode for the electrochemical determination of 2,4-dichlorophenol [J] . Ann Maria C G,Akshaya K B,Sherin Rison,Anitha Varghese,Louis George. Synthetic Metals . 2020 (C)
Orientated growth of Copper-based MOF for acetylene storage [J] . Zhanke Wang,Lei Ge,Mengran Li,Rijia Lin,Hao Wang,Zhonghua Zhu. Chemical Engineering Journal . 2018
An electrochemical sensor based on copper-based metal-organic frameworks-graphene composites for determination of dihydroxybenzene isomers in water [J] . Jun Li,Jianfei Xia,Feifei Zhang,Zonghua Wang,Qingyun Liu. Talanta . 2018
High sensitive and selective graphene oxide/molecularly imprinted polymer electrochemical sensor for 2,4-dichlorophenol in water [J] . Yiming Liang,Lanlan Yu,Ran Yang,Xiao Li,Lingbo Qu,Jianjun Li. Sensors & Actuators: B. Chemical . 2017
Elimination of Methylene Blue and Reactive Black 5 from Aqueous Solution Using HKUST-1 [J] . Loera Serna S.,Solis H.,Ortiz E.,Martínez Hernandéz A. L.,Nore?a L.. International Journal of Environmental Science and Development . 2017 (4)
Synthesis of poly(sodium 4-styrenesulfonate) functionalized graphene/cetyltrimethylammonium bromide (CTAB) nanocomposite and its application in electrochemical oxidation of 2,4-dichlorophenol [J] . Jianjun Li,Dandan Miao,Ran Yang,Lingbo Qu,Peter de B. Harrington. Electrochimica Acta . 2014
Well-studied Cu-BTC still serves surprises: evidence for facile Cu2+/Cu+ interchange. [J] . Szanyi Janos,Daturi Marco,Clet Guillaume,Baer Donald R,Peden Charles H F. Physical chemistry chemical physics : PCCP . 2012 (13)
Chlorophenols and other related derivatives of environmental concern: Properties, distribution and microbial degradation processes [J] . Ademola O. Olaniran,Etinosa O. Igbinosa. Chemosphere . 2011 (10)
Simultaneous determination of dihydroxybenzene and phenylenediamine positional isomers using capillary zone electrophoresis coupled with amperometric detection. [J] . Dong Shuqing,Chi Langzhu,Yang Zhiyong,He Pingang,Wang Qingjiang,Fang Yuzhi. Journal of separation science . 2009 (18)
Biosensor based on paraffin/graphite modified with sweet potato tissue for the determination of hydroquinone in cosmetic cream in organic phase [J] . Iolanda Cruz Vieira,Orlando Fatibello-Filho. Talanta . 2000 (4)
Method for the analysis of 4-nitrophenol and parathion in soil using supercritical fluid extraction and immunoassay [J] . Wong Jennifer M.,Li Qing Xiao,Hammock Bruce D.,Seiber James N.. Journal of Agricultural and Food Chemistry . 1991 (10)
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