WANG Weiyuan, SHI Zhuo. Research on fabrication and gas sensitive properties of CuO-SnO2 flower-like structure composite material[J]. 2020, (3): 18-21.
WANG Weiyuan, SHI Zhuo. Research on fabrication and gas sensitive properties of CuO-SnO2 flower-like structure composite material[J]. 2020, (3): 18-21. DOI: 10.13873/J.1000-9787(2020)03-0018-04.
CuO-SnO2花状结构复合材料的制备及气敏特性研究
摘要
采用简单的一步水热合成路线制备了CuO-SnO
2
花状结构复合材料
通过SEM
XRD
XPS对相应的微观结构进行了分析表征。结果显示:所制备的花状结构由形状、大小相似的纳米片组装而成
直径为2~5μm
CuO的含量对SnO
2
花状结构没有影响。将制得的花状结构复合材料构筑旁热式气敏元件
并采用静态配气法测试了气敏元件对三甲胺气体的敏感特性。结果表明:相比于纯Sn O
2
元件
CuO-SnO
2
元件对三甲胺气体表现出灵敏度高、检测下限低、选择性好、响应和恢复迅速等优点
其气敏性能的提高归因于SnO
2
与CuO接触面p-n异质结的构筑及CuO的催化特性。
Abstract
CuO-SnO
2
flower-like composite material are successfully fabricated through a facile one-step hydrothermal synthesis route. The structural and composition information are examined by means of X-ray diffractometer( XRD)
field emission scanning electron microscopy( FESEM)
and X-ray photoelectron spectroscopy( XPS). The result indicates that the obtained CuO-SnO
2
flower-like structure are assembled by a number of nanosheets of similar shapes and sizes
with diameters range of 2~ 5 μm. Content of CuO has no effect on SnO
2
flower-like structure. The obtained composite material is used to construc
t an indirectly heated gas sensor
and the sensitivity characteristics of the gas sensor to trimethylamine gas are tested by a static gas distribution method. The experimental results show that compared to pure SnO
2
sensor
CuO-SnO
2
senor displays high sensitivity
low detecting limit
good selectivity
and fast response and recovery to trimethylamine gas. The enhanced gas sensitive properties are probably attributed to the formation of p-n heterojunctions at interface and the catalytic characteristics of CuO.