原位铋修饰掺硼金刚石电极检测分析锌离子

高成耀; 佟建华; 边超; 孙楫舟; 李洋; 夏善红

doi:10.13873/J.1000-9787(2017)10-0010-04

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原位铋修饰掺硼金刚石电极检测分析锌离子

研究与探讨 | 更新时间：2025-09-11

- 原位铋修饰掺硼金刚石电极检测分析锌离子
- Detection and analysis on Zn（Ⅱ） ion by in-situ bismuth modified boron-doping diamond electrode
- 传感器与微系统 2017年36卷第10期页码：10-13
- 作者机构：
  
  1. 中国科学院电子学研究所传感技术国家重点实验室
  2. 中国人民武装警察部队学院指挥系
- 作者简介：
- 基金信息：
  
  国家重点基础研究发展“973”计划资助项目（2015CB352100）;国家自然科学基金资助项目（61306010）
- DOI：10.13873/J.1000-9787(2017)10-0010-04
  中图分类号： O614.241;O657.1
- 纸质出版：2017
- 稿件说明：
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[1]高成耀,佟建华,边超,孙楫舟,李洋,夏善红.原位铋修饰掺硼金刚石电极检测分析锌离子[J].传感器与微系统,2017,36(10):10-13.

GAO Cheng-yao, TONG Jian-hua, BIAN Chao, et al. Detection and analysis on Zn（Ⅱ） ion by in-situ bismuth modified boron-doping diamond electrode[J]. 2017, 36(10): 10-13.
[1]高成耀,佟建华,边超,孙楫舟,李洋,夏善红.原位铋修饰掺硼金刚石电极检测分析锌离子[J].传感器与微系统,2017,36(10):10-13. DOI： 10.13873/J.1000-9787(2017)10-0010-04.

GAO Cheng-yao, TONG Jian-hua, BIAN Chao, et al. Detection and analysis on Zn（Ⅱ） ion by in-situ bismuth modified boron-doping diamond electrode[J]. 2017, 36(10): 10-13. DOI： 10.13873/J.1000-9787(2017)10-0010-04.

摘要

以原位铋修饰掺硼金刚石（BDD）电极为传感电极对锌离子进行检测分析

方法迅速、简便、绿色环保。相对裸电极原位铋修饰BDD电极

锌离子响应电流信号有较大提高。考察了扫描方式、铋离子浓度、电极硼掺杂浓度对锌离子传感分析的影响

优化了传感分析中脉冲频率和尺寸、支持电解液p H值、沉积电位、沉积时间等参数。锌离子浓度与溶出峰电流值在50

00μg/L范围内呈线性关系

Abstract

A rapid

easy

environmentally friendly and sensitive anodic stripping voltammetric method with a bismuth in-situ modified boron-doping diamond（ BDD） electrode is developed for the determination of Zn（ II）ion. In presence of bismuth ion

the sensitivity for the determination of Zn（ II） is remarkably enhanced. Effect parameters such as scan mode

bismuth concentration

boron-doping concentrations of BDD electrode

pulse size

pulse frequency

p Hs

preconcentration potential and time are investigated. Under the optimal conditions

the stripping peak currents increase linearly with increasing concentrations of Zn（ II） ion in the range of 50

00 μg/L. Correlation coefficient is 0. 9979

limit of detection is 2. 32 μg/L

for Zn（ II） ion（ S/N = 3）. The interference experiments show that common ions have little influence on the determination except Cu（ II） ion. The electrode displays a good repeatability.

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references

光纤水质传感器的研究现状和发展趋势 [J]. 吴刚,刘月明,楼俊. 传感器与微系统 . 2012(10)

传感器技术在金属检测中的新发展 [J]. 潘勇,傅慧娟,黄慧萍,林克英,肖红艳. 传感器与微系统 . 2006(07)

硼掺杂对金刚石薄膜生长特性的影响 [J]. 刘卫平,余庆选,田宇全,廖源,王冠中,方容川. 无机材料学报 . 2005(05)

Influence of boron content on the morphological, spectral, and electroanalytical characteristics of anodically oxidized boron-doped diamond electrodes [J] . Karolina Schwarzová-Pecková,Jana Vosáhlová,Ji?í Barek,Ivana ?loufová,Ewa Pavlova,Václav Petrák,Jaroslava Zavázalová. Electrochimica Acta . 2017

Electrochemical sensors for the simultaneous determination of zinc, cadmium and lead using a Nafion/ionic liquid/graphene composite modified screen-printed carbon electrode [J] . Sudkate Chaiyo,Eda Mehmeti,Kristina ?agar,Weena Siangproh,Orawon Chailapakul,Kurt Kalcher. Analytica Chimica Acta . 2016

Effects of Boron Doping on the Propertiesof Ultrananocrystalline Diamond Films [J] . Wen-Xiang Yuan,Q. X. WU,Z. K. Luo,H. S. Wu. Journal of Electronic Materials . 2014 (4)

Determination of trace metals by anodic stripping voltammetry using a bismuth-modified carbon nanotube electrode [J] . Gil Ho Hwang,Won Kyu Han,Joon Shik Park,Sung Goon Kang. Talanta . 2008 (2)

Linear sweep anodic stripping voltammetry of heavy metals from nitrogen doped tetrahedral amorphous carbon thin films [J] . N.W. Khun,E. Liu. Electrochimica Acta . 2008 (10)

Preconcentration with 1-Nitroso-2-naphthol Complexes on Dowex MWC-1 Resin: Determination of Cu and Zn at Trace Level in Drinking Water Samples by ICP-AES [J] . A. Demir Mulazimoglu,I. E. Mulazimoglu,E. Ozkan. E-Journal of Chemistry . 2008 (4)

Anodic Stripping Voltammetry of Heavy Metals at Nanocrystalline Boron‐Doped Diamond Electrode [J] . Electroanalysis . 2007 (11)

A comparison of boron-doped diamond thin-film and Hg-coated glassy carbon electrodes for anodic stripping voltammetric determination of heavy metal ions in aqueous media [J] . Elizabeth A. McGaw,Greg M. Swain. Analytica Chimica Acta . 2006 (2)

Determination of calcium, magnesium and zinc in unused lubricating oils by atomic absorption spectroscopy [J] . A.P. Udoh. Talanta . 1995 (12)

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