上海交通大学 电子信息与电气工程学院,上海,200240
纸质出版:2025
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陶登虎, 奚馨, 沈超超, 等. 有序介孔碳/碳纤维海洋电场传感电极研究[J]. 传感器与微系统, 2025,44(12):28-32+37.
TAO Denghu, XI Xin, SHEN Chaochao, et al. Study of ordered mesoporous carbon/carbon fiber sensing electrodes for marine electric field[J]. 2025, 44(12): 28-32+37.
为改善碳纤维(CF)电极比电容小、自噪声大、低频电场响应弱的问题,采用高温碳化其表面共组装形成的酚醛树脂—嵌段共聚物(Resol-F127)薄膜的方法,制备了一种新型表面包覆有序介孔碳的CF(OMC/CF)复合电极。通过形貌观察得到OMC在CF表面呈现出有序的二维六方排布结构,孔径约为16nm,极大增加了复合电极的比表面积,促使提高比电容(37.1F/g),降低电荷转移电阻和低频容抗。在电场响应方面,OMC的包覆有利于增强对0.01~1Hz的低频电场响应,促进改善波形信号响应的精准性、灵敏度、线性度,电极自噪声可降至0.73nV/Hz
1/2
@1Hz,有利于水下微弱低频信号探测。该OMC/CF复合电极的开发为高灵敏、低自噪声海洋电场电极的研制提供了新的思路。
To address the problem of small specific capacitance
large self-noise
and weak electric field response and of carbon fiber(CF)electrodes
a novel ordered mesoporous carbon coated CF(OMC/CF)composite electrode is prepared by the high temperature carbonization of the phenolic resin-block copolymer(Resol-F127)film
which is co-assembly formed on the surface CF.The OMC exhibits a two-dimensional hexagonal arrangement with a pore size of about 16nm
which greatly increases the specific surface area of the composite electrode
promoting the increase of high specific capacitance(37.1F/g)and the reduction of
charge transfer resistance and capacitive reactance.In terms of electric field response
the coated OMC is beneficial to improve the response to low-frequency electric field range of 0.01~1Hz
obtaining the improvement of waveform signal response in the accuracy
sensitivity and linearity and the electrode self-noise can be reduced to 0.73nV/Hz
1/2
@1Hz
which is conducive to the detection of weak low-frequency signals underwater.The preparation of the OMC/CF composite electrode provides a new approach for the innovative development of high-performance marine electric field electrodes with high sensitivity and low self-noise.
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