太原理工大学 纳米能源与器件研究中心,山西,太原,030024
纸质出版:2025
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耿爱森, 李银辉, 李廷鱼, 等. 基于SIS复合膜的超弹性压电纳米发电机研究[J]. 传感器与微系统, 2025,44(11):18-22.
GENG Aisen, LI Yinhui, LI Tingyu, et al. Research on hyperelastic piezoelectric nanogenerator based on SIS composite membrane[J]. 2025, 44(11): 18-22.
基于压电陶瓷和压电聚合物组装的压电纳米发电机(PENG),由于其较差的弹性,限制了其在可穿戴设备和植入设备等领域的应用。为此,基于超弹性材料苯乙烯—异戊二烯—苯乙烯嵌段共聚物(SIS)和镓铟合金液态金属可拉伸电极制备了兼具良好的贴附性和高压电输出特性的SIS/钛酸钡(BTO)复合弹性PENG,研究结果表明:当BTO掺杂质量分数为20%时,SIS/BTO复合弹性PENG输出性能最优,输出电压可达9.62V,电流为657nA,比纯SIS的弹性PENG分别提高了2倍和2.8倍,输出功率可达2.25μW,断裂伸长率高达1276%。并且SIS/BTO复合弹性PENG经过5000次循环敲击测试,输出电压没有明显下降,复合弹性PENG输出性能稳定。同时,将SIS/BTO复合弹性PENG贴合到人体关节处,可以对关节弯曲进行实时监测。表明:该SIS/BTO复合弹性PENG具有良好的弹性和生物相容性,有望在可植入和可穿戴电子设备中得到广泛应用。
The poor elasticity of piezoelectric nanogenerator(PENG)assembled based on piezoelectric ceramics and piezoelectric polymers limits its application in wearable devices and implantable devices.Therefore
styrene-isoprene-styrene(SIS)/barium titanate(BTO)composite elastic PENG based on the superelastic material SIS block copolymer and gallium indium alloy liquid metal stretchable electrodes are prepared
which exhibit excellent adhesion and high-voltage output characteristics.The research results indicate that when the BTO doping mass fraction is 20wt%
the SIS/BTO composite elastic PENG has the optimal output performance
with an output voltage of 9.62V and a current of 657nA
which are 2 times and 2.8 times higher than the pure SIS elastic PENG
respectively
and an output power of 2.25μW.The elongation at break is as high as 1276%.And after 5000 cycles of impact testing
the output voltage of SIS/BTO composite elastic PENG does not significantly decrease
and the output performance of the composite elastic PENG is stable.Meanwhile
by attaching SIS/BTO composite elastic PENG to the joints of the human body
real-time monitoring of joint bending can be achieved.This indicates that the SIS/BTO composite elastic PENG has good elasticity and biocompatibility
and is expected to be widely used in implantable and wearable electronic devices.
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